BHXFZ - ID 08610KUA-GD, BLACK 37030, ZENTHANE

Product Identification

Product ID:ID 08610KUA-GD, BLACK 37030, ZENTHANE
MSDS Date:02/08/1990
FSC:8010
NIIN:01-229-7540
MSDS Number: BHXFZ

Responsible Party
HERBERT-VERKAMP-CALVERT CHEM. CO.
4600 DUES DRIVE
CINCINNATI, OH 45246-1009
US

Emergency Phone: 513-874-9261

Info Phone: 513-874-9261

Preparer: JANE FREEMAN

Cage: 1HD53

Contractor
HERBERT-VERKAMP-CALVERT CHEMICAL
18642 CINCINNATI, OH 45246-1009 US

Telephone: 513-874-9261

Cage: 1HD53

Ingredients

METHYL ISOAMYL KETONE

CAS: 110-12-3

RTECS: MP3850000

Fraction By Weight: 31.15%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM; 9293


PREPOLYMER OF HEXAMETHYLENE DIISOCYANATE

Fraction By Weight: 30-40%


SILICA, CRYSTALLINE - QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 20-30%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293


BLACK IRON OXIDE PIGMENT (NUISANCE DUST)

CAS: 1317-61-9

Fraction By Weight: 5-10%


N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 1.29%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS


1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: <0.05%

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB


AROMATIC HYDROCARBONS (MIXTURE OF C8'S-C10'S)

CAS: 64742-95-6

Fraction By Weight: 1.22%

Hazards

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ISOCYANATE CAUSES RESPIRATORY
SENSITIZATION, ASTHMA-LIKE SYMPTOMS &/OR SKIN SENSITIZATION,
ALLERGIC DERMATITIS, RASH, ITCH, HIVES & SWELLING TO EXTREMITIES.
REPORTED PROLONGED/REPEATED OVEREXPOSURE MA Y CAUSE PERMANENT BRAIN
& NERVOUS SYSTEM DAMAGE, LIVER & KIDNEY DAMAGE. SILICA: MAY CAUSE
LUNG INJURY IF NOT PROTECTED.
Explanation of Carcinogenicity:BASED ON LAB ANIMAL DATA IARC HAS LISTED
SILICA AS A "PROBABLE HUMAN CARCINOGEN".
Effects of Overexposure:MAY CAUSE IRRITATION TO SKIN, EYES &
RESPIRATORY TRACT (NOSE, THROAT, LUNGS). SYMPTOMS MAY BE WATERING
EYES, DRYNESS OF THROAT, COUGHING, HEADACHE, TIGHTNESS IN CHEST OR
BURNING SENSATION. HEADACHE, D IZZINESS OR NAUSEA MAY BE
EXPERIENCED BY SOME AS A RESULT OF EXPOSURE TO SOLVENTS.
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
AILMENTS; CHEMICAL SENSITIZATION.

First Aid

First Aid:VAPORS: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM
AND QUIET. NOTIFY A PHYSICIAN. EYES: FLUSH IMMEDIATELY WITH LARGE
AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES. TAKE TO A DOCTOR.
REMOVE CONTAMINATED CLOTHING. CONSULT A PHYSICIAN. INGESTION: IF
SWALLOWED, CALL A PHYSICIAN IMMEDIATELY.

Fire Fighting

Flash Point Method:TCC
Flash Point:60 F/15 C
Autoignition Temp:Autoignition Temp Text:840 F
Lower Limits:0.5
Upper Limits:8.2
Extinguishing Media:FOAM, DRY CHEMICAL, CO2.
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIP WITH SCBA. DURING A
FIRE, IRRITATING & HIGHLY TOXIC GASES (SEE REACTIVITY DATA) & SMOKE
ARE PRESENT FROM DECOMP/COMBUSTION PRODUCTS.
Unusual Fire/Explosion Hazard:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELEC EQUIP, SPARK, ETC. CLOSED CONTAINER MAY EXPLODE
FROM EXTREME HEAT OR BURST FROM WATER. RESIDUE MAY IGNITE

Accidental Release

Spill Release Procedures:EVACUATE NON-ESSENTIAL PERSONS. REMOVE ALL
SOURCES OF IGNITION (FLAMES, HOT SURFACES, ELECTRICAL, STATIC OR
FRICTIONAL SPARKS). VENTILATE AREA. AVOID BREATHING VAPORS. COVER
SPILL WITH INERT ABSORBENT . POUR NEUTRALIZING AGENT OVER
SPILLAGE--ALLOW**
Neutralizing Agent:3-8% CONC AMMONIA/2% DETERG/90-95% WATER;OR SOLUTION
OF U.C TERGITOL TMN-***

Handling

Handling and Storage Precautions:DO NOT STORE ABOVE 120F OR BELOW 32F.
STORE LARGE QUANTITIES IN BLDG DESIGNED TO COMPLY WITH OSHA
1910.106. KEEP AWAY FROM SPARKS & OPEN FLAME. ****
Other Precautions:***10 (20%) & WATER (80%). KEEP CONTAINERS TIGHTLY
CLOSED & PROTECT FROM MOISTURE. IF MOISTURE ENTERS, PRESSURE CAN
BUILD DUE TO REACTION PRODUCING CO2, CAN SEAL CONTAINER TO PRESSURE
& BURST. DO NOT RESEAL IF CONTAMINATION IS SUSPECTED.

Exposure Controls

Respiratory Protection:SURGEON GENERAL REQUIRES AIRLINE RESPIRATOR TO
BE USED UNLESS AIR SAMPLING SHOWS EXPOS BELOW OSHA LIMIT. THEN CHEM
CARTRIDGE OR AIRLINE RESPIRATORS ARE REQUIRED. SAME PRECAUTION
SHOULD BE USED DURING MIXING OR OPERATIONS WHERE FUMES PRESENT
Ventilation:GEN DILUTION/LOCAL EXHAUST VENT IN VOL/PATTERN TO KEEP LEV
BELOW TLV. REMOVE DECOMP PRODUCTS DURING WELD & FLAME CUTTING
Protective Gloves:CHEMCIAL RESISTANT GLOVES.
Eye Protection:SAFETY EYEWEAR/SPLASH GUARD/SIDE SHIELDS
Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN
CONTACT AT A MINIMUM.
Work Hygienic Practices:WASH HANDS & ANY EXPOSED SKIN THOROUGHLY BEFORE
EATING OR SMOKING. SMOKE IN SMOKING AREAS ONLY.
Supplemental Safety and Health
DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED WHEN POURING.
AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES. USE WITH
ADEQUATE VENTILATION & RESPIRATORY EQUIPMENT. EMPTIED CONTAINERS
MAY R ETAIN HAZARD RESIDUE OR EXPLOSIVE VAPORS. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING.

Chemical Properties

HCC:F2
Boiling Pt:B.P. Text:>244F,>118C
Vapor Pres:8.00
Vapor Density:> THAN AIR
Spec Gravity:1.216
Viscosity:65-68 KREBS
Evaporation Rate & Reference:EQUAL TO BUTYL ACETATE
Solubility in Water:REACTS WITH WATER
Appearance and Odor:OPAQUE LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume:51.32

Stability

Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, GLYCOL ETHERS, AMINES.
Stability Condition to Avoid:WATER CONTAMINATION.
Hazardous Decomposition Products:BY FIRE: CO2, CO, OXIDES OF NITROGEN,
TRACES OF HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANATE.

Disposal

Waste Disposal Methods:FOLLOW LOCAL, STATE & FEDERAL REGS: INCINERATION
PREFERRED METHOD.(**TO REACT AT LEAST 10 MIN, COLLECT MATERIAL
W/NON-SPARK TOOLS INTO OPEN CONTAINER, ADD MORE NEUTRAL AGENT, WASH
AREA THEN FLUSH W/WA TER. MOVE CONTAINER TO SAFE PLACE, COVER
LOOSELY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.